Palladium Supported on Calcined Coconut Shell Fiber (Pd/CCSF) as an Efficient and Sustainable Catalyst: Microwave-Assisted Synthesis of C–S Cross-Coupling Derivatives in DMF

Ramesh Katla; Rakhi Katla; Gabriela Kern; Clarissa H. Rosa; Gilber R. Rosa

doi:10.1055/a-2732-6914

Synthesis, Table of Contents

Synthesis
DOI: 10.1055/a-2732-6914

Paper

Palladium Supported on Calcined Coconut Shell Fiber (Pd/CCSF) as an Efficient and Sustainable Catalyst: Microwave-Assisted Synthesis of C–S Cross-Coupling Derivatives in DMF

Authors

Ramesh Katla

¹School of Chemistry and Food, Federal University of Rio Grande, Rio Grande, Brazil (Ringgold ID: RIN67820)

²School of Medicine, University of Virginia, Charlottesville, United States (Ringgold ID: RIN2358)
Rakhi Katla

³FACET, Universidade Federal da Grande Dourados, Dourados, Brazil (Ringgold ID: RIN186079)
Gabriela Kern

⁴Department of Chemistry, Universidade Federal do Rio Grande, Santo Antônio da Patrulha, Brazil (Ringgold ID: RIN67820)
Clarissa H. Rosa

⁴Department of Chemistry, Universidade Federal do Rio Grande, Santo Antônio da Patrulha, Brazil (Ringgold ID: RIN67820)
Gilber R. Rosa

⁴Department of Chemistry, Universidade Federal do Rio Grande, Santo Antônio da Patrulha, Brazil (Ringgold ID: RIN67820)

Abstract

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Abstract

The palladium supported on calcined coconut shell fiber (Pd/CCSF) catalyst was synthesized using an eco-friendly agro-industrial material, CCSF, with PdCl₂ supported on it. This catalyst was used for the first time in the development of a C–S cross-coupling reaction between various benzene thiols and 4,7-dibromo-2,1,3-benzothiadiazole or 5-bromo-2,1,3-benzothiadiazole under microwave irradiation at 75 °C (200 W, 100 psi) in DMF, with K₂CO₃ as the base. The catalyst was characterized using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) analyses. Furthermore, it was recycled and reused for up to four catalytic cycles without any loss of efficiency. A proposed mechanistic pathway for the C–S cross-coupling reaction is also included in this article.

Keywords

Palladium - Coconut Shell Fiber (CCSF) - Cross-coupling - Benzene thiols - MWI

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References

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