Efficient Preparation of Polyunsaturated and Functionalized Acetylenic Ketones from Alkynylmanganese Bromides

Abstract

α,β-Acetylenic ketones are efficiently prepared, under mild conditions, by reacting alkynylmanganese compounds with acyl chlorides. The procedure is especially useful for preparing polyfunctionalized and polyunsaturated α,β-acetylenic ketones.

organomanganese - acylation - acetylenic ketones - acyl chlorides

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