Palladium-Catalyzed Propargylic Substitution with Phosphorus
Nucleophiles

doi:10.1055/s-0030-1259418

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Synfacts 2011(3): 0307-0307
DOI: 10.1055/s-0030-1259418

Metal-Mediated Synthesis

Palladium-Catalyzed Propargylic Substitution with Phosphorus Nucleophiles

Contributor(s): Paul Knochel, Andreas J. Wagner
M. Kalek, T. Johansson, M. Jezowska, J. Stawinski*
Stockholm University, Sweden and Polish Academy of Sciences, Poznan, Poland

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Publication History

Publication Date:
16 February 2011 (online)

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Significance

A new palladium(0)-catalyzed reaction of propargylic derivatives with phosphorus nucleophiles is reported. Various allenyl phosphonates are obtained with defined stereochemistry both in the allenic and the phosphonate moiety.