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Synfacts 2011(3): 0295-0295
DOI: 10.1055/s-0030-1259494
DOI: 10.1055/s-0030-1259494
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Synergistic Catalysis of Chiral Gold Complexes and Chiral Anions
K. Aikawa, M. Kojima, K. Mikami*
Tokyo Institute of Technology, Japan
Further Information
Publication History
Publication Date:
16 February 2011 (online)
Significance
This paper describes a new synergistic catalyst system consisting of a chiral BIPHEP-gold complex and a chiral anion. The catalyst system is capable of catalyzing the intramolecular hydroalkoxylation of allenes.