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Synfacts 2011(11): 1197-1197  
DOI: 10.1055/s-0031-1289184
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Tandem Catalytic Allylic Amination and [2,3]-Stevens Rearrangement of Tertiary Amines

Contributor(s): Hisashi Yamamoto, Susumu Oda
A. Soheili, U. K. Tambar*
The University of Texas Southwestern Medical Center at Dallas, USA
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Publikationsverlauf

Publikationsdatum:
19. Oktober 2011 (online)

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Significance

The authors described the first ­example of an intermolecular allylic amination of tertiary amines and subsequent [2,3]-Stevens ­rearrangement. The tandem ammonium ylide generation/[2,3]-Stevens rearrangement gave access to a wide range of complicated amino acid derivatives with good yield and diastereoselectivity.