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Synfacts 2011(12): 1344-1344  
DOI: 10.1055/s-0031-1289355
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Synthesis of Trifluoroethyl-Substituted Ketones

Contributor(s): Paul Knochel, Nadja M. Barl
B. Morandi, E. M. Carreira*
ETH Zürich, Switzerland
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Publikationsdatum:
18. November 2011 (online)

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Significance

This work discloses new strategies in aldehyde homologation, accomplished by the reaction of aliphatic and aromatic aldehydes as well as cyclic ketones with in situ generated F3CCHN2, furnishing trifluoroethyl-substituted ­ketones.