Synthesis, Table of Contents Synthesis 2012; 44(9): 1410-1416DOI: 10.1055/s-0031-1290504 paper © Georg Thieme Verlag Stuttgart · New YorkA Concise Synthesis of 3-Arylated Di- and Tetrahydro-2H-2-benzazepin-1-ones; A New Synthetic Approach to the Homoprotoberberine Framework Authors Author Affiliations Stéphane Lebrun a Université Lille Nord de France, 59000 Lille, France, Fax: +33(3)20436309 Email: axel.couture@univ-lille1.fr b USTL, Laboratoire de Chimie Organique Physique, EA CMF 4478, Bâtiment C3(2), 59655 Villeneuve d’Ascq Cedex, France Axel Couture* a Université Lille Nord de France, 59000 Lille, France, Fax: +33(3)20436309 Email: axel.couture@univ-lille1.fr c CNRS, UMR 8181 ‘UCCS’, Bâtiment C3(2), 59655 Villeneuve d’Ascq Cedex, France Eric Deniau a Université Lille Nord de France, 59000 Lille, France, Fax: +33(3)20436309 Email: axel.couture@univ-lille1.fr b USTL, Laboratoire de Chimie Organique Physique, EA CMF 4478, Bâtiment C3(2), 59655 Villeneuve d’Ascq Cedex, France Pierre Grandclaudon a Université Lille Nord de France, 59000 Lille, France, Fax: +33(3)20436309 Email: axel.couture@univ-lille1.fr b USTL, Laboratoire de Chimie Organique Physique, EA CMF 4478, Bâtiment C3(2), 59655 Villeneuve d’Ascq Cedex, France Recommend Article Abstract Buy Article(opens in new window) All articles of this category(opens in new window) Abstract A variety of 3-arylated di- and tetrahydro-2H-2-benzazepin-1-ones were efficiently assembled through a sequence involving a Suzuki–Miyaura cross-coupling reaction with enol phosphates derived from the corresponding benzazepine-1,3-diones. 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