Preparation of Pentafluorinated Phenyl-Monohydro[60]fullerenes

Abstract

Pentafluorinated phenyl-monohydro[60]fullerenes [C₆₀(Ar_f)₅H] are synthesized in good yields via reaction of the corresponding fluorinated phenyl copper reagent, itself prepared in situ from the fluorinated phenyl Grignard reagent (Ar_fMgBr) and copper(I) bromide–dimethyl sulfide complex, with [60]fullerene (C₆₀) in 1,2-dichlorobenzene under a nitrogen atmosphere.

Keywords

fullerene - fluorinated phenyl - copper reagent - regioselective - five-fold addition

• References

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