Magnetite–Sulfuric Acid Magnetic Nanoparticles: Preparation and Applica­tion in Synthesis of Mono-, Bis-, and Tris-14H-Dibenzo[a,j]xanthen-14-yl­arenes under Solvent-Free Conditions

Ali Reza Karimi; Zeinab Dalirnasab; Marzie Karimi

doi:10.1055/s-0033-1338595

Synthesis, Table of Contents

Synthesis 2014; 46(07): 917-922
DOI: 10.1055/s-0033-1338595

paper

Magnetite–Sulfuric Acid Magnetic Nanoparticles: Preparation and Application in Synthesis of Mono-, Bis-, and Tris-14H-Dibenzo[a,j]xanthen-14-ylarenes under Solvent-Free Conditions

Authors

Ali Reza Karimi*

Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran Fax: +98(861)4173406 Email: a-karimi@araku.ac.ir
Zeinab Dalirnasab

Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran Fax: +98(861)4173406 Email: a-karimi@araku.ac.ir
Marzie Karimi

Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran Fax: +98(861)4173406 Email: a-karimi@araku.ac.ir

Abstract

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Abstract

Novel magnetite–sulfuric acid (Fe₃O₄·SO₃H) magnetic nanoparticles were prepared by the direct reaction of chlorosulfonic acid with magnetite nanoparticles, and characterized by IR spectroscopy, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy. The catalytic activity of the Fe₃O₄·SO₃H nanoparticles in the reaction of 2-naphthol with aryl mono-, di- and trialdehydes was examined, and these catalysts were shown to exhibit remarkable catalytic performance in the solvent-free synthesis of mono-, bis-, and tris-14H-dibenzo[a,j]xanthen-14-ylarenes. The catalyst retained its activity for several cycles.

Key words

polycycles - heterocycles - catalysts - heterogeneous catalysis - condensation - cyclizations

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Magnetite–Sulfuric Acid Magnetic Nanoparticles: Preparation and Applica­tion in Synthesis of Mono-, Bis-, and Tris-14H-Dibenzo[a,j]xanthen-14-yl­arenes under Solvent-Free Conditions

Authors

Magnetite–Sulfuric Acid Magnetic Nanoparticles: Preparation and Application in Synthesis of Mono-, Bis-, and Tris-14H-Dibenzo[a,j]xanthen-14-ylarenes under Solvent-Free Conditions