Synthesis 2013; 45(15): 2150-2154
DOI: 10.1055/s-0033-1338924
paper
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Novel Octahedral Silicon Compounds; Synthesis of Bis[3-(1-{[aryl(hydroxy)methylene]hydrazinylidene}ethyl)-6-methyl-2-oxo-2H-pyran-4-olato-N,O,O′]silicon(IV)

Authors

  • Sotiria Karamouzi

    a   Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   eMail: kotali@eng.auth.gr
  • Anna Maniadaki

    a   Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   eMail: kotali@eng.auth.gr
  • Despina A. Nasiopoulou

    a   Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   eMail: kotali@eng.auth.gr
  • Elvira Kotali

    a   Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   eMail: kotali@eng.auth.gr
  • Antigoni Kotali*

    a   Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   eMail: kotali@eng.auth.gr
  • Philip A. Harris

    b   GlaxoSmithKline, 1250 South Collegeville Road, P.O. Box 5089, Collegeville, PA 19426-0989, USA
  • James Raftery

    c   The School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK
  • John A. Joule

    c   The School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK
Weitere Informationen

Publikationsverlauf

Received: 13. Dezember 2012

Accepted after revision: 06. Mai 2013

Publikationsdatum:
24. Juni 2013 (online)


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Abstract

The synthesis of new silicon compounds is reported via the cyclization of dehydroacetic acid N-acylhydrazones with silicon tetraacetate. The procedure involves formation of new octahedral hexacoordinated silicon structures.

Supporting Information