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Synthesis 2016; 48(13): 2105-2111
DOI: 10.1055/s-0035-1561951
DOI: 10.1055/s-0035-1561951
paper
Palladium-Catalyzed Nitration of Arenes by 1,2,3-Triazole-Directed C–H Activation
Autoren
Weitere Informationen
Publikationsverlauf
Received: 09. Januar 2016
Accepted after revision: 26. Februar 2016
Publikationsdatum:
06. April 2016 (online)
Abstract
An efficient palladium-catalyzed regioselective nitration of 1,4-disubstituted 1,2,3-triazoles has been described with good functional group compatibility, using Pd(OAc)2 as the catalyst and NaNO2 as the nitration source, leading to the synthesis of 1,2,3-triazoles containing nitro groups in good to excellent yields.
Key words
palladium - C–H activation - 1,4-disubstituted 1,2,3-triazoles - nitration - regioselectivitySupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561951.
- Supporting Information (PDF) (opens in new window)
-
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