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Synthesis 2017; 49(18): 4350-4356
DOI: 10.1055/s-0036-1588487
DOI: 10.1055/s-0036-1588487
paper
Copper-Catalyzed Arylation of Benzothiazoles with Toluene Derivatives: Synthesis of 2-Arylbenzothiazole
Authors
The authors thank the National Natural Science Foundation of China (Nos: 21472121, 21272148) and the State Key Laboratory of Applied Organic Chemistry, Lanzhou University for financial support.
Further Information
Publication History
Received: 22 April 2017
Accepted after revision: 05 June 2017
Publication Date:
25 July 2017 (online)
Abstract
A copper-catalyzed reaction of benzothiazole and readily available toluene derivatives has been disclosed. This protocol is proposed to proceed through the oxidation of toluene and ring opening of benzothiazole, thus providing a new pathway for the synthesis of 2-arylbenzothiazoles.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1588487.
- Supporting Information (PDF) (opens in new window)
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