Synthesis 2017; 49(16): 3710-3719
DOI: 10.1055/s-0036-1588786
paper
© Georg Thieme Verlag Stuttgart · New York

Nucleophilic Addition of Amides to 10-Alkylacridinium Cations: A Case of Double N-Nucleophilicity of Some Monoamides

Oleg P. Demidov
Department of Chemistry, North Caucasus Federal University, Pushkin st. 1, Stavropol, 355009, Russian Federation   Email: ivborovlev@rambler.ru
,
Gulminat A. Amangasieva
Department of Chemistry, North Caucasus Federal University, Pushkin st. 1, Stavropol, 355009, Russian Federation   Email: ivborovlev@rambler.ru
,
Elena K. Avakyan
Department of Chemistry, North Caucasus Federal University, Pushkin st. 1, Stavropol, 355009, Russian Federation   Email: ivborovlev@rambler.ru
,
Ivan V. Borovlev*
Department of Chemistry, North Caucasus Federal University, Pushkin st. 1, Stavropol, 355009, Russian Federation   Email: ivborovlev@rambler.ru
› Author Affiliations
Supported by: This project received financial support from the Ministry of Education and Science of the Russian Federation (4.6306.2017/BP).
Further Information

Publication History

Received: 07 March 2017

Accepted after revision: 23 March 2017

Publication Date:
18 April 2017 (online)


Abstract

An effective synthesis of N-(10-alkyl-9,10-dihydroacridin-9-yl) derivatives of amides, ureas, and urethanes has been developed. Additionally, the spatially overloaded molecules of N,N-bis(10-alkyl-9,10-dihydroacridin-9-yl)acrylamide were obtained in the case of formamide and acrylamide.

Supporting Information

 
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