Synthesis 2017; 49(13): 2980-2984
DOI: 10.1055/s-0036-1588993
paper
© Georg Thieme Verlag Stuttgart · New York

Synthesis of β-Nitro Ketones by Chemoselective Reduction of β-Nitro Enones under Solid Heterogeneous Catalysis

Serena Gabrielli
Green Chemistry Group, School of Sciences and Technology, Chemistry Division, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy   Email: alessandro.palmieri@unicam.it
,
Elena Chiurchiù
Green Chemistry Group, School of Sciences and Technology, Chemistry Division, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy   Email: alessandro.palmieri@unicam.it
,
Susanna Sampaolesi
Green Chemistry Group, School of Sciences and Technology, Chemistry Division, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy   Email: alessandro.palmieri@unicam.it
,
Roberto Ballini
Green Chemistry Group, School of Sciences and Technology, Chemistry Division, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy   Email: alessandro.palmieri@unicam.it
,
Alessandro Palmieri*
Green Chemistry Group, School of Sciences and Technology, Chemistry Division, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy   Email: alessandro.palmieri@unicam.it
› Author Affiliations
Further Information

Publication History

Received: 07 February 2017

Accepted after revision: 13 March 2017

Publication Date:
18 April 2017 (online)


Abstract

A new, simple and efficient chemoselective reduction of β-nitro enones to provide substituted β-nitro ketones, a strategic class of compounds, under solid heterogeneous palladium catalysis and in the presence of triethylsilane is presented.

Supporting Information

 
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