Synthesis of Corannulenes Revisited

Timothy M. Swager; Kosuke Yoshinaga

doi:10.1055/s-0037-1611454

RSS-Feed abonnieren

Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.

https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml

Teilen / Bookmarken

Facebook Linkedin Weibo

PDF herunterladen

Synfacts 2019; 15(01): 0032
DOI: 10.1055/s-0037-1611454

Synthesis of Materials and Unnatural Products

Synthesis of Corannulenes Revisited

Rezensent(en):

Timothy M. Swager

,

Kosuke Yoshinaga

Scott LT. * Hashemi MM, Meyer DT, Warren HB. University of Nevada, Reno, USA
Corannulene. A Convenient New Synthesis.

J. Am. Chem. Soc. 1991;
113: 7082-7084

Crossref Suche in Google Scholar

Weitere Informationen

Publikationsverlauf

Publikationsdatum:
14. Dezember 2018 (online)

Abstract
Volltext
Abbildungen

als PDF herunterladen Lizenzen und Reprints

Key words

corannulenes - flash vacuum pyrolysis - polycyclic aromatic hydrocarbons

Significance

In 1991, Scott and co-workers reported a convenient synthesis of corannulene. Corannulenes are interesting because of their unique optoelectronic properties arising from their bowl-shaped structure. The production of corannulene is currently possible on a kilogram scale, and corannulene has found many applications in materials.

Comment

Flash vacuum pyrolysis of the tetrabromide intermediate also resulted in corannulene. The unprecedented carbon NMR spectrum of corannulene exhibited three peaks.

Lizenzen und Reprints