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Synthesis 2020; 52(13): 1959-1968
DOI: 10.1055/s-0039-1690870
DOI: 10.1055/s-0039-1690870
paper
Mn(III)-Mediated Facile Access to Polysubstituted α-Naphthols from β-Keto Ester Derivatives and Terminal Alkynes
We thank the West Light Foundation of the Chinese Academy of Sciences and the Natural Science Foundation of Guizhou Province of China (QKHJC[2017]1117, QKHJC[2018]1109, and QKHPTRC[2017]5718).
Weitere Informationen
Publikationsverlauf
Received: 07. März 2020
Accepted after revision: 09. März 2020
Publikationsdatum:
26. März 2020 (online)
Abstract
A novel manganese-mediated reaction for the synthesis of polysubstituted α-naphthols has been developed from β-keto esters and terminal alkynes. This system holds the advantages of readily available starting materials and mild conditions. Mechanistic investigations revealed that this reaction proceeds via a tandem radical cyclization process.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690870.
- Supporting Information
- CIF File
-
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