A Magnetically Recyclable Palladium-Catalyzed Formylation of Aryl Iodides with Formic Acid as CO Source: A Practical Access to Aromatic Aldehydes

Shengyong You; Rongli Zhang; Mingzhong Cai

doi:10.1055/s-0040-1706621

Synthesis, Table of Contents

Synthesis 2021; 53(11): 1962-1970
DOI: 10.1055/s-0040-1706621

paper

A Magnetically Recyclable Palladium-Catalyzed Formylation of Aryl Iodides with Formic Acid as CO Source: A Practical Access to Aromatic Aldehydes

Shengyong You

^aKey Laboratory of Functional Small Organic Molecule, Ministry of Education and College of Chemistry & Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China

^bInstitute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang 330029, P. R. of China

,

Rongli Zhang

^aKey Laboratory of Functional Small Organic Molecule, Ministry of Education and College of Chemistry & Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China

,

Mingzhong Cai ∗

^aKey Laboratory of Functional Small Organic Molecule, Ministry of Education and College of Chemistry & Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China

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Abstract

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Abstract

A magnetically recyclable palladium-catalyzed formylation of aryl iodides under CO gas-free conditions has been developed by using a bidentate phosphine ligand-modified magnetic nanoparticles-anchored palladium(II) complex [2P-Fe₃O₄@SiO₂-Pd(OAc)₂] as catalyst, yielding a wide variety of aromatic aldehydes in moderate to excellent yields. Here, formic acid was employed as both the CO source and the hydrogen donor with iodine and PPh₃ as the activators. This immobilized palladium catalyst can be obtained via a simple preparative procedure and can be facilely recovered simply by using an external magnetic field, and reused at least 9 times without any apparent loss of catalytic activity.

Key words

formylation - palladium - magnetic nanoparticles - heterogeneous catalysis - aromatic aldehyde

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References

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