Environmentally-Friendly TEMPO-Mediated Oxidation of Alcohols with Poly[4-(diacetoxyiodo)styrene]

Kenji Sakuratani; Hideo Togo

doi:10.1055/s-2003-36248

SHORTPAPER

Environmentally-Friendly TEMPO-Mediated Oxidation of Alcohols with Poly[4-(diacetoxyiodo)styrene]

Kenji Sakuratani^a, Hideo Togo*^a,b
^a Graduate School of Science and Technology, Faculty of Science, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522, Japan
^b Department of Chemistry, Faculty of Science, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522 Japan
e-Mail: togo@scichem.s.chiba-u.ac.jp;

Abstract

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Abstract

Primary and secondary alcohols were successfully oxidized to the corresponding aldehydes and ketones in good yields, respectively, with poly[4-(diacetoxyiodo)styrene] (PSDIB) in the presence of TEMPO (cat.) in acetone, as an environment-friendly method.

Key words

poly[4-(diacetoxyiodo)styrene] (PSDIB) - oxidation - aldehyde - ketone - environment

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References

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