An Efficient Route to Aliphatic 2,2-Dichloroaldehydes via Chlorination of Aldehydes or Alcohols with the System Cl2/Quaternary Ammonium Chloride

Franco Bellesia; Laurent De Buyck; Franco Ghelfi; Ugo M. Pagnoni; Andrew F. Parsons; Adriano Pinetti

doi:10.1055/s-2003-41078

PAPER

An Efficient Route to Aliphatic 2,2-Dichloroaldehydes via Chlorination of Aldehydes or Alcohols with the System Cl₂/Quaternary Ammonium Chloride

Franco Bellesia^a, Laurent De Buyck*^b, Franco Ghelfi*^a, Ugo M. Pagnoni^a, Andrew F. Parsons^c, Adriano Pinetti^a
^a Dipartimento di Chimica, Università degli Studi di Modena e Reggio Emilia, via Campi 183, 41100 Modena, Italy
Fax: +39(59)373543; e-Mail: ghelfi.franco@unimo.it.;
^b Department of Organic Chemistry, Faculty of Agricultural and Applied Biological Sciences, University of Gent, Coupure Links 653, 9000 Gent, Belgium
^c Department of Chemistry, University of York, Heslington, York YO10 5DD, UK

Abstract

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Abstract

An effective and low waste method for preparing aliphatic 2,2-dichloroaldehydes has been achieved by halogenation of aldehydes or alcohols with Cl₂, using tetraalkylammonium chlorides as recoverable catalysts.

Key words

alcohols - aldehydes - halogen - halogenation - halide

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References

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