A Novel Synthesis of New 3-Aryl-7-methylpyrano[4,3-b]pyran-4H,5H-diones Using Hypervalent Iodine(III) Reagents

Om Prakash; Ajay Kumar; Anil K. Sadana; Shiv P. Singh

doi:10.1055/s-2005-921751

SHORTPAPER

A Novel Synthesis of New 3-Aryl-7-methylpyrano[4,3-b]pyran-4H,5H-diones Using Hypervalent Iodine(III) Reagents

Om Prakash*, Ajay Kumar, Anil K. Sadana*, Shiv P. Singh
Chemistry Department, Kurukshetra University, Kurukshetra, Haryana 136119, India
Fax: +91(1744)238277; e-Mail: dromprakash50@rediffmail.com; e-Mail: sadana@rice.edu;

Abstract

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Abstract

Oxidation of 3-cinnamoyl-4-hydroxy-6-methyl-2H-pyran-2-ones with [hydroxy(tosyloxy)iodo]benzene in CH₂Cl₂ leads to cyclization, thereby providing a new and convenient route for the synthesis of 3-aryl-7-methylpyrano[4,3-b]pyran-4H,5H-diones.

Key words

hypervalent iodine - [hydroxy(tosyloxy)iodo]benzene - oxidation - chalcone - dehydroacetic acid

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References

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