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Synthesis 2006(15): 2585-2589
DOI: 10.1055/s-2006-942469
DOI: 10.1055/s-2006-942469
PAPER
© Georg Thieme Verlag Stuttgart · New York
Pd-Catalyzed Amination of Chloro-Terpyridine for the Preparation of Amine-Containing Ruthenium(II) Complexes
Further Information
Received
3 February 2006
Publication Date:
04 July 2006 (online)
Publication History
Publication Date:
04 July 2006 (online)
Abstract
The palladium-catalyzed amination reaction of commercially available 4′-chloro-2,2′:6′,2′′-terpyridine opens an easy access to aminated mono- and ditopic terpyridine ligands. The obtained compounds were subsequently used to prepare new amine-containing ruthenium(II) polypyridyl complexes.
Key words
palladium-catalyzed amination - terpyridine - ruthenium - photochemistry - switches
- 1
Baranoff E.Collin J.-P.Flamigni L.Sauvage J.-P. Chem. Soc. Rev. 2004, 33: 147 - 2
Andres PR.Schubert US. Adv. Mater. 2004, 16: 1043 - 3
Constable EC.Handel RW.Housecroft CE.Farrán Morales A.Ventura B.Flamigni L.Barigelletti F. Chem. Eur. J. 2005, 11: 4024 - 4
Medlycott EA.Hanan GS. Chem. Soc. Rev. 2005, 34: 133 ; and references cited therein -
5a
Martineau D.Beley M.Gros P. J. Org. Chem. 2006, 71: 566 -
5b
Wang J.Fang Y.-Q.Hanan GS.Loiseau F.Campagna S. Inorg. Chem. 2005, 44: 5 -
5c
Martineau D.Gros P.Beley M.Fort Y. Eur. J. Inorg. Chem. 2004, 3984 - 6
Johansson O.Lomoth R. Chem. Commun. 2005, 1578 - 7
Wolfe JP.Wagaw S.Marcoux J.-F.Buchwald SL. Acc. Chem. Res. 1998, 31: 805 -
8a
Shen Q.Shekhar S.Stambuli JP.Hartwig JF. Angew. Chem. Int. Ed. 2005, 44: 1371 -
8b
Ji J.Li T.Bunnelle WH. Org. Lett. 2003, 5: 4611 -
8c
Wolfe JP.Tomori H.Sadighi JP.Yin J.Buchwald SL. J. Org. Chem. 2000, 65: 1158 -
9a
Charles MD.Schultz P.Buchwald SL. Org. Lett. 2005, 7: 3965 -
9b
Hooper MW.Hartwig JF. Organometallics 2003, 22: 3394 -
9c
Hooper MW.Utsunomiya M.Hartwig JF. J. Org. Chem. 2003, 68: 2861 -
9d
Ogawa K.Radke KR.Rothstein SD.Rasmussen SC. J. Org. Chem. 2001, 66: 9067 -
10a
Ruloff R.van Koten G.Merbach AE. Chem. Commun. 2004, 842 -
10b
Fallahpour R.-A. Synthesis 2003, 155 -
10c
Whittle B.Batten SR.Jeffery JC.Rees LH.Ward MD. J. Chem. Soc., Dalton Trans. 1996, 4249 -
11a
Wieprecht T,Schlingloff G,Xia J,Heinz U,Schneider A,Dubs M.-J,Bachmann F,Hazenkamp M, andDannache J. inventors; PCT Int. Appl. WO2004/039933 A1. ; Chem. Abstr. 2004, 140, 408683 -
11b
Wieprecht T.Xia J.Heinz U.Dannacher J.Schlingloff G. J. Mol. Catal. A: Chem. 2003, 203: 113 -
11c
Constable EC.Cargill Thompson AMW.Tocher DA.Daniels MAM. New J. Chem. 1992, 16: 855 -
12a
Fallahpour R.-A.Neuburger M.Zehnder M. New J. Chem. 1999, 53 -
12b
Fallahpour R.-A. Eur. J. Inorg. Chem. 1998, 1205 - 13
Barder TE.Walker SD.Martinelli JR.Buchwald SL. J. Am. Chem. Soc. 2005, 127: 4685 - 14
Ziessel R.Grosshenny V.Hissler M.Stroh C. Inorg. Chem. 2004, 43: 4262 - 15
Abrahamsson M.Wolpher H.Johansson O.Larsson J.Kritikos M.Eriksson L.Norrby P.-O.Bergquist J.Sun L.Åkermark B.Hammarström L. Inorg. Chem. 2005, 44: 3215 - 16
Ward MD. Chem. Soc. Rev. 1995, 24: 121 - 17
Evans IP.Spencer A.Wilkinson G. J. Chem. Soc., Dalton Trans. 1973, 204 - 18
Johansson O.Borgström M.Lomoth R.Palmblad M.Bergquist J.Hammarström L.Sun L.Åkermark B. Inorg. Chem. 2003, 42: 2908