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Synthesis 2006(17): 2873-2878
DOI: 10.1055/s-2006-942525
DOI: 10.1055/s-2006-942525
PAPER
© Georg Thieme Verlag Stuttgart · New YorkA Green and Straightforward Synthesis of 4′-Substituted Terpyridines
Further Information
Received
28 March 2006
Publication Date:
25 July 2006 (online)
Publication History
Publication Date:
25 July 2006 (online)
Abstract
A set of 4′-substituted 2,2′:6′,2′′-terpyridines has been synthesized in a one-pot procedure under environmentally friendly reaction conditions using PEG and aqueous ammonia as solvents. This procedure features a short synthetic route, short reaction times, easy work-up, and good yields in comparison to conventional methods. The crystallographic data reveal the influence of the 4′-aryl substituent on the molecular structure and π-stacking behavior of the respective terpyridines.
Key words
green chemistry - heterocycles - ligands - multicomponent reactions - terpyridines
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References
CCDC 296109 and 296110 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.