Conversion of a Vinyl Grignard Reagent to a 1,2-Dimetalated Ethane Synthon

doi:10.1055/s-2008-1077798

RSS-Feed abonnieren

Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.

https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml

Teilen / Bookmarken

Facebook Linkedin Weibo

PDF herunterladen

Synfacts 2008(6): 0636-0636
DOI: 10.1055/s-2008-1077798

Metal-Mediated Synthesis

Conversion of a Vinyl Grignard Reagent to a 1,2-Dimetalated Ethane Synthon

Contributor(s): Paul Knochel, Tobias Thaler
R. Tanaka, H. Sanjiki, H. Urabe*
Tokyo Institute of Technology, Yokohama, Japan

Weitere Informationen

Publikationsverlauf

Publikationsdatum:
21. Mai 2008 (online)

Lizenzen und Reprints

Significance

A synthon for 1,2-dimetalated ethane was efficiently synthesized by the reaction of CpYH₂ with vinyl Grignard reagent. It was used in the reaction with triple C-C bonds carboxylic esters.