DOI: 10.1055/s-00000131

Synfacts

Issue 02 · Volume 2011 · February 2011 DOI: 10.1055/s-002-21628

Synform

A11
SYNFORM ISSUE 2011/02

Synthesis of Natural Products and Potential Drugs

z119
All PDFs of this category
0119
Synthesis of Telcagepant
0120
Synthesis of MK-8141
0121
Total Synthesis of (+)-Roxaticin
0122
Synthesis of Pestalone and Pestalalactone
0123
Synthesis of (+)-Chaetocin A
0124
Synthesis of (+)- and (-)-Fluvastatin
0125
Synthesis of (+)-Lycoflexine
0126
Synthesis of Lactimidomycin
0127
Total Synthesis of Isokidamycin
0128
Synthesis of a CCK1 Receptor Antagonist
0129
Synthesis of (-)-209I and (-)-223J
0130
Synthesis of Zanamivir Congeners

Synthesis of Heterocycles

z131
All PDFs of this category
0131
Au/Ag-Catalyzed Synthesis of 3-Fluorofurans
0132
Acid-Catalyzed Rearrangement of Ureido-dihydrofurans to N-Pyrrole Ureas
0133
Enantioselective Synthesis of Dihydrofurans Using Dynamic Kinetic Resolution
0134
Copper-Catalyzed Ullmann-Type Coupling Route to Quinazolines
0135
Synthesis of Oxazoles via TBHP/I2-Mediated Reaction of Alkenes with Benzylic Amines
0136
Silver-Catalyzed Synthesis of 2-Amino-imidazole Alkaloids
0137
NHC-Catalyzed Michael Addition for the Synthesis of Dihydropyranones
0138
A Nickel-Catalyzed [2+2+1]-Cycloaddition Approach to Lactams
0139
Synthesis of 2-Aminobenzoxazoles from 2-Aminophenols
0140
Synthesis of Fused Thiophene-Isoxazoles from 2-Alkynyl-3-Nitro-Thiophenes
0141
Synthesis of 1,4-Benzothiazepin-5-ones from N-Tosyl Aziridines and 2-Iodothiophenols
0142
Synthesis of Isoindolones from Imines and ortho-Iodobenzoyl Acid Chlorides
0143
Directed ortho-Metalation-Halocyclization Route to Benzothiophenes
0144
Palladium-Catalyzed Heterannulation Synthesis of 3-Borylated Indoles
0145
Tertiary Amine Catalyzed Annulation Route to Tetrasubstituted Pyrans

Synthesis of Materials and Unnatural Products

z147
All PDFs of this category
0147
Controlling Supramolecular Chirality
0148
Perfluorobenzene Captures Fullerene
0149
Supramolecular Glow-Sticks
0150
Pillar[5]arenes
0151
Unquenched Fluorescent Metal Nanocages
0152
Polyelectrolytes: Fluorescence Turn-On Sensors in Aqueous Media
0153
(2,1-a)-Indenofluorene with Clapping Fluorenes
0154
Cheap Precursor for Arynes
0155
Microwaveable Calixarenes
0156
Polycyclic Imide Derivatives: Getting in Tune with Your Inner LUMO
0157
Bicyclononynes: New Ring-Strained Alkynes for Bioorthogonal Labeling
0158
Facile Synthesis of Benzobisthioxanthene
0159
Novel Synthesis of Tetrabenzocoronenes
0160
Black to Transmissive Electrochromic Polymers
0161
Synthesis of Functionalized Pentacenes from Isobenzofurans

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z163
All PDFs of this category
0163
Stereoselective Iodocarbocyclization
0164
Intermolecular Hydroacylation of Homoallylic Sulfides
0165
Enantioselective Synthesis of 2-Carboxy Cyclic Ethers
0166
The Effect of β-Substituents in Aldol Reactions of Boron Enolates
0167
Design of a New Six-Membered NHC Ligand for Copper-Catalyzed β-Borylation
0168
Enantioenriched Allyl Esters via Lipase-Vanadium Combo Catalysis
0169
Enantioselective syn Hydration of Enones in Water Using a DNA-Based Catalyst
0170
Alkene Alkoxycarbonylation Using Novel Chiral Dipalladium Catalysts
0171
Chiral Fluoride Generator and Its Application in Kinetic Resolution
0172
Enantioselective Synthesis of Planar Chiral Arene Chromium Complexes
0173
Asymmetric Synthesis of Tertiary Stereogenic Centers
0174
Titanium-Catalyzed Reaction of Alkenylboron Reagents with Aldehydes
0175
Selective aza-Barbier Allylations of N-tert-Butanesulfinylimines
0176
Rare Earth Metal Catalyzed Asymmetric Intermolecular Hydroamination
0177
Lewis Base Catalyzed Asymmetric Aldol Addition of Oxyketene Imines to Aldehydes
0178
Copper-Catalyzed Synthesis of 3-Aminoindoles and Pyrroloindolines
0179
Synthesis of Chiral Cyclohexenones Using a Multicomponent Reaction
0180
Nickel-Catalyzed [2+2+2] Cycloaddition of Isocyanates and Allenes
0181
Domino Synthesis of Complex Tetrahydropyrans
0182
Synthesis of Chiral Tertiary Organoboronic Esters by Conjugate Addition
0183
Enantioselective Synthesis of C2 and C1 Dienes
0184
Neodymium-Catalyzed Asymmetric Synthesis of 1,3-Bis(hydroxymethyl)-2-oxindoles
0185
Enantioselective Copper-Catalyzed Intramolecular Carboamination of Alkenes
0186
Copper-Catalyzed Asymmetric Allylic Substitution with Arylaluminum Reagents
0187
Hydrogen Bond Assisted Asymmetric Metal Catalysis
0188
Asymmetric Hydrogenation of Fluorinated Imines
0189
Iridium-Catalyzed Enantioselective Ring Opening of Azanorbornene Derivatives
0190
Enantioconvergent Synthesis of Allyl Boronates
0191
Dynamic Kinetic Resolution under Ruthenium-Catalyzed Transfer Hydrogenation
0192
Enantioselective Desymmetrization of Cyclopropenes

Metal-Mediated Synthesis

z193
All PDFs of this category
0193
β-Selective Arylation of Thiophenes
0194
3,3-Bissilyl Carbonyl and Enol Derivatives via Brook Rearrangement
0195
Stereospecific Cross-Coupling of Secondary Alkyl Trifluoroborates
0196
Palladium(II)-Catalyzed Decarboxylative Addition of Benzoic Acids to Nitriles
0197
Coupling of N-Tosylhydrazone, Terminal Alkyne, and Aryl Halide
0198
Control of Product Selectivity in Ruthenium-Catalyzed C-H Arylation
0199
A Multiligand-Based Palladium Catalyst for C-N Cross-Coupling Reactions
0200
Coupling of Indium Homoenolates with Acid Chlorides
0201
Palladium-Catalyzed Decarboxylative Cross-Coupling of 2-Phenylbenzoic Acids
0202
Palladium-Catalyzed Cyanation of Aryl Mesylates
0203
Iron-Catalyzed Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles
0204
Palladium-Catalyzed Cross-Coupling with Hydrazine
0205
Iridium-Catalyzed ortho-Silylation of Arenes by Hydroxyl-Directed C-H Activation
0206
Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to Allyl Sulfones
0207
Copper-Catalyzed Direct Carboxylation of C-H Bonds Using Carbon Dioxide

Organo- and Biocatalysis

z209
All PDFs of this category
0209
NHC-Catalyzed C-H Alkylation of Aldehydes
0210
Asymmetric α-Alkylation of Cyanocarbolines by Phase-Transfer Catalysis
0211
α-Allylation of Aldehydes via a Conjugate Addition-Elimination Pathway
0212
Betaine-Catalyzed Synthesis of Cyclic Carbonates
0213
NHC-Catalyzed Intramolecular Redox Lactamization
0214
An Efficient Entry to Chiral Pyrroloindolines
0215
Chiral Guanidinium-Catalyzed Enantioselective Claisen Rearrangement
0216
A New Chiral Primary Amine Catalyst: Application in Conjugate Additions
0217
2-Hydroxyalkyl, 2-Aminoalkyl Furanes, and 2,3-Dihydrofuranes
0218
Michael Addition of β-Ketosulfones to Nitroalkenes
0219
SPINOL-Derived Phosphoric Acids for Addition of Indoles to Imines
0220
A Highly Efficient Approach to Chiral Homoaldols
0221
An Asymmetric Domino Aza-Morita-Baylis-Hillman/Aza-Michael Reaction

Polymer-Supported Synthesis

z223
All PDFs of this category
0223
Asymmetric Addition of Diethyl Zinc to Benzaldehydes with Ti(Oi-Pr)4 and NS(a)
0224
Flow Hydroalkylation of Styrenes under Microwave Irradiation
0225
Wittig Reactions Using a Bifunctional Polymeric Reagent
0226
A Supported Organic Catalyst for Asymmetric Michael Addition
0227
Fluorination with Polystyrene-Supported Iodobenzenes in Ionic Liquid
0228
Dehydration of Amides with Hydrotalcite-Supported Vanadium Catalyst
0229
Aerobic Epoxidation of Stilbene with Copper on FePt Nanowires
0230
Aqueous Suzuki-Miyaura Coupling with Palladium Nanoparticles/BMI-TFSI
0231
TEMPO-Coated Fe3O4 Nanoparticles for Selective Oxidation of Alcohols
0232
N-Formylation of Amines with Methanol or Formalin Using Gold Nanoclusters
0233
Solid-Phase Total Synthesis of Symplocamide A
0234
Acetalization with Methanol Using Metal-Organic Frameworks
0235
Solid-Phase Synthesis of an Amino Imidazotriazine Library

Addenda and Errata

0236
Alkenylative Cross-Coupling between Alkyl Sulfides and Grignard Reagents