DOI: 10.1055/s-00000131

Synfacts

Issue 02 · Volume 10 · February 2014 DOI: 10.1055/s-004-26302

Synform

  • A17

    SYNFORM ISSUE 2014/02

    • Synthesis of Natural Products and Potential Drugs

  • z111

    All PDFs of this category

  • 0111

    Synthesis of (S)-Sitagliptin

  • 0112

    Total Synthesis of (+)-Methyl N-Decarbomethoxychanofruticosinate

  • 0113

    Biogenetically Inspired Synthesis of Indole Alkaloids

  • 0114

    Total Synthesis of Montanine-Type Alkaloids

  • 0115

    Synthesis of a Glucokinase Activator

  • 0116

    Total Synthesis of (±)-Gephyrotoxin

  • 0117

    Synthesis of Diaryl Sulfones: GSK 742457

  • 0118

    Synthesis of Thuggacin B

  • 0119

    Synthesis of Voriconazole

  • 0120

    Synthesis of GSK2263167

  • 0121

    Synthesis of Renin Inhibitor DS-8108b

  • 0122

    Synthesis of (±)-Sculponeatin N

  • 0123

    Synthesis of Safingol

  • 0124

    Synthesis of (+)-Bermudenynol

    • Synthesis of Heterocycles

  • z125

    All PDFs of this category

  • 0125

    Heteroannulation Route to Benzofurans

  • 0126

    Three-Component Synthesis of Rhodanines on Nanoporous Silica

  • 0127

    Synthesis of Benzofuranones from Alkynyl Aryl Ethers

  • 0128

    Transformation of Sulfonylpyrroles into 6-Azaindoles

  • 0129

    Iron(III) Chloride Catalyzed Synthesis of Spirocyclic Pyrimidinones

  • 0130

    Ir(III)/Bi(OTf)3-Catalyzed Prins Route to Pyran-Fused Indoles

  • 0131

    Synthesis of Substituted Thiophenes from Polyhalogenated Nitrobutadienes

  • 0132

    Palladium-Catalyzed Heteroannulation Route to 3-Trifluoromethylbenzofurans

  • 0133

    Rhodium-Catalyzed Synthesis of Furo[2,3-b]pyran-6-ones

  • 0134

    Synthesis of 2,5-Dihydrofurans via a Petasis Borono-Mannich Reaction

  • 0135

    Rhodium-Catalyzed ortho-C–H Acylation Route to 3-Alkylidenephthalides

  • 0136

    Synthesis of 1,3-Thiazin-2-ones via an Asymmetric Hetero-Diels–Alder Reaction

  • 0137

    Asymmetric Organocatalytic Synthesis of 2,6-Diazabicyclo[2.2.2]octanones

  • 0138

    C4-Alkenylation of 3-Formyl Indoles via Ruthenium(II)-Catalyzed C–H Activation

  • 0139

    Synthesis of Piperazines via Gold-Catalyzed Cyclization of Propynyl Diamines

    • Synthesis of Materials and Unnatural Products

  • z141

    All PDFs of this category

  • 0141

    Having a Hydrocarbon Ball

  • 0142

    Aminyl Tetraradicals Persist at Room Temperature

  • 0143

    Four-in-One: Pentafulvalenes via Quadruple Carbopalladation

  • 0144

    Gold-Catalyzed Diastereoselective Synthesis of Naphtha[b]cyclobutenes

  • 0145

    Zipping Up Thienylbenzenes to Thia[7]helicenes

  • 0146

    Two Stable Extended Zethrenes

  • 0147

    A Stable, Intra-Sheet π-Conjugated Covalent Organic Framework

  • 0148

    A New Record for Proton Sponges

  • 0149

    A π-Extended Indenofluorene with Substantial Singlet Biradical Character

  • 0150

    Tetracenes in a Bowl-Shaped Arrangement

  • 0151

    Programmed Synthesis of Arylthiazoles

  • 0152

    High Yielding Synthesis of meso-Substituted Macrocycles

  • 0153

    A Simple Reagent for the Difluoroethenylation of Arenes

    • Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

  • z155

    All PDFs of this category

  • 0155

    Asymmetric Allylic Alkylation of Acyclic β‑Keto Esters Catalyzed by Iridium

  • 0156

    Asymmetric Addition of Phosphines Catalyzed by P-Chiral Pd Complexes

  • 0157

    Enantioselective [3+2] Annulation via C–H Activation Catalyzed by Iridium

  • 0158

    Enantioselective Hydrogenation of Nitroolefins by Rhodium Catalysis

  • 0159

    [3+3] Cycloaddition of Azomethine Ylides with Azomethine Imines

  • 0160

    Synthesis of Axially Chiral Biaryls by a Palladium Catalyst

  • 0161

    Asymmetric Ring Opening of Oxabenzonorbornadiene with Amines

  • 0162

    Asymmetric Synthesis of QUINAP via Atropselective C–P Coupling

  • 0163

    Iron–Schiff Base Catalyzed Asymmetric Hydrophosphonylation

  • 0164

    Asymmetric [3+2] Cycloaddition of Disubstituted Nitroalkenes

  • 0165

    Kinetic Resolution of Racemic Propargyl Acetates by Palladium Catalysis

  • 0166

    Yttrium-Catalyzed Asymmetric Aldol Cyclization of α-Keto Esters

  • 0167

    Asymmetric Synthesis of 1,2,4-Triazinane Frameworks by Copper Catalysis

  • 0168

    Enantioselective Copper-Catalyzed Oxytrifluoromethylation of Alkenes

  • 0169

    Enantioselective Synthesis of γ-Methyl-Substituted Carbonyl Compounds

  • 0170

    Asymmetric Sulfoxidation Catalyzed by Mn/Porphyrin

  • 0171

    Asymmetric Synthesis of Axially Chiral Biaryls via [2+2+2] Cycloaddition

  • 0172

    Co(II)-Based Metalloradical Catalysis for Asymmetric Cyclopropanation

  • 0173

    Asymmetric Reduction of 2,2-Dimethyl-4-dioxinones Catalyzed by Ruthenium

  • 0174

    Copper-Catalyzed Enantioselective Intramolecular Cannizzaro Reaction

  • 0175

    Subsequent Reduction and Jocic-Type Reaction of Trichloromethyl Ketones

  • 0176

    Ir-Catalyzed Asymmetric Hydrogenation and Transfer Hydrogenation of Ketones

  • 0177

    Rhodium-Catalyzed Enantioselective Hydrogenation of 1-Alkylvinyl Benzoates

  • 0178

    Deoxycholic Acid Derived Biaryl Phosphites in Conjugate Addition

  • 0179

    [3+3] Cycloaddition of Enol Diazoacetates with N-Acyliminopyridinium Ylides

  • 0180

    Asymmetric Conjugate Addition of Arylboronic Acids to Nitroolefins

  • 0181

    Dehydrogenative Cross-Coupling of Simple Alkenes and Acrylates

  • 0182

    Bisheterocyclizations of Alkynes Catalyzed by Platinum

  • 0183

    Iron-Catalyzed Asymmetric Ring Opening of meso-Epoxides

    • Metal-Mediated Synthesis

  • z185

    All PDFs of this category

  • 0185

    N–Bpin-Directed Borylation of (Hetero)Aryls

  • 0186

    Fluorination of Aryl Trifluoroboronates with Potassium Fluoride Mediated by Copper

  • 0187

    Enantiospecific Transition-Metal-Catalyzed Allylic Alkylation

  • 0188

    1,4-Reductive Aldol Reactions of Substituted α,β-Unsaturated Amides

  • 0189

    Reductive Coupling and Reduction of Barbituric Acids Using SmI2

  • 0190

    Allylation of N-(Quinolin-8-yl)benzamides with Allyl Ethers Catalyzed by Iron

  • 0191

    Cyanotrifluoromethylation of Styrenes Using the Togni Reagent and Copper Cyanide

  • 0192

    Electrophilic Difluoro(phenylthio)methylation of Allyltrimethylsilanes

  • 0193

    gem-Difluoroolefination of Diazo Compounds with TMSCF3 Catayzed by Copper

  • 0194

    Cross-Coupling of Silanes with Organic Halides Catalyzed by Copper

  • 0195

    Reactions of 2-Pyrone Derivatives with MeMgBr Catalyzed by Iron

  • 0196

    Synthesis of 2-Boryl 1,3-Butadienes from α-Alkoxy Allenes Catalyzed by Copper

  • 0197

    Substitution of Unactivated Alkyl Fluorides Using YbI3

  • 0198

    Base-Dependent Enantiodivergent De-protonation/Acylation of α-Amino Nitriles

  • 0199

    One-Pot Synthesis of Polysubstituted Isochromanes

    • Organo- and Biocatalysis

  • z201

    All PDFs of this category

  • 0201

    β-Substituted α-Hydroxy Esters via Dynamic Kinetic Resolution

  • 0202

    Boronate Ester Assisted Chiral Carboxylic Acid Catalyzed Aziridination

  • 0203

    Direct β-Functionalization of Ketones by Photoredox-Coupled Organocatalysis

  • 0204

    A Chiral Tertiary Amine Catalyzed Intermolecular [3+2] Annulation

  • 0205

    Conjugate-Base-Stabilized Brønsted Acids in Asymmetric Catalysis

  • 0206

    An Organocatalytic Route towards Annulated Indoles

  • 0207

    Axially Chiral Amine Catalyzed Asymmetric Hydroxyamination of Aldehydes

  • 0208

    Organocatalytic Remote Activation in an Aza-Diels–Alder Reaction

  • 0209

    Asymmetric Counteranion-Directed Photoredox Catalysis

  • 0210

    Two Fluorinated Compounds from One Organocatalytic Kinetic Resolution

  • 0211

    Asymmetric Catalytic α-Benzylation of Aldehydes

  • 0212

    Asymmetric Synthesis of Pyrroloindolones by N-Heterocyclic Carbenes

    • Polymer-Supported Synthesis

  • z213

    All PDFs of this category

  • 0213

    Click Reaction with Copper(I)–NHC Supported on Fe3O4/Si

  • 0214

    Asymmetric Hydrogenation of Ketones with a PMO-Supported Rhodium Complex

  • 0215

    PS-PAr3 Hybrid: Metal Complexation and Catalytic Applications

  • 0216

    Direct Amidation from Alcohols and Amines with Polymeric Au or Au/Co

  • 0217

    Photocatalyzed Deoxygenation of Styrene Oxides Using TiO2

  • 0218

    Strecker and Kabachnik–Fields Reactions with DHAA/Fe3O4

  • 0219

    Asymmetric Aldol Reaction Using a Polymeric Hydantoin Auxiliary

  • 0220

    Flow Oppenauer Oxidation of Alcohols with Zirconia Oxide

  • 0221

    Glassy Carbon-Supported Rhodium(I) Catalysts for Intramolecular Hydroamination

  • 0222

    Enantioselective Aldol Reaction in Water with a Supported Prolinamide

  • 0223

    Synthesis of Benzoyl Fumarates with Supported Nicotinic Acid Thioester

  • 0224

    Aerobic Oxidation with Branched Polystyrene-Supported Gold NPs