Synfacts

Issue 06 · June 2017

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4-Diazoisochroman-3-imines and 3,5-Dihydroisochromeno-[3,4-d][1,2,3]triazoles

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A Radical Choreography: Make One, Get One Free

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Gearing Up for Switchable Machines

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Stepwise Two-Photon Photochemical Reactions

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Cyclo- versus Conjugate Addition: H-Bond Control Over a One-Pot Multistep Reaction

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Semiconducting Polymer Dots

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Enantioselective Palladium(II)-Catalyzed Borylation FREE ACCESS

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Copper-Catalyzed Enantioselective Trifluoromethylarylation of Styrenes

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Palladium-Catalyzed Vinylborylation of Alkenes FREE ACCESS

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0604
Iridium-Catalyzed Asymmetric C–C Bond-Forming Transfer Hydrogenation

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0605
Desymmetrization of meso-Anhydrides by Dual Catalysis

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Iridium-Catalyzed Asymmetric Hydrogenation of γ-Hydroxylactams

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Synthesis of Five-Membered Ring through an Alkynylation/Cyclization Step

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Rhodium-Catalyzed Enantioselective Isomerization of meso-Oxabicycles

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Rhodium-Catalyzed Enantioselective Synthesis of Spiropyrazolones

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0610
Palladium-Catalyzed Enantioselective Syn-thesis of Chiral Biaryl Compound Precursors

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0611
Ruthenium-Catalyzed Asymmetric Hydrogenation of Aryl N-Heteroaryl Ketones

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Hydrogenation of Cyclic Imines by a Cationic Ruthenium Diamine Catalyst

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0613
Enantioselective Synthesis of Isochromenes by Copper/Ruthenium Tandem Catalysis

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0614
Iridium-Catalyzed Asymmetric Reductive Amination of Aliphatic Ketones

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0615
Asymmetric Organo-Metal Cooperative Catalysis

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0616
Stereoselective Mizoroki–Heck Alkenylations and Arylations

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Enantioselective Addition of Enynes to Ketones

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0618
Ruthenium-Catalyzed DKR of Benzofuranones by Transfer Hydrogenation

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Palladium-Catalyzed Synthesis of Chiral Allylboron Reagents

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Rhodium-Catalyzed Asymmetric Isomerization of Allylic Alcohols

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0621
Synthesis of Chiral γ-Lactams by Asymmetric Hydrogenation

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0622
Rhodium-Catalyzed Enantioselective Synthesis of Succinic Anhydrides

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0623
Ruthenium-Catalyzed Enantioselective Si–H Bond Insertion

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0624
Palladium-Catalyzed Enantioselective Carbene Insertion

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0625
Exclusive Metal-Centered Chirality for Asymmetric Catalysis

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0626
Asymmetric Formal [3+2] Cycloaddition Catalyzed by a Chiral Cobalt(II) Complex

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Synthesis of Epoxypyrrolidines by [2+1] Cycloaddition

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Palladium-Catalyzed Stereoselective C–H Olefination of Biaryls

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0629
Zinc-Catalyzed Enantioselective Alkyne Addition

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Olefination of Sulfonyl Halides and Esters

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0632
para-Selective C–H Borylation of Benzamides and Pyridines

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0633
Stereoselective Synthesis of Alkylidene Cyclopentylamines

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0634
Stereocontrolled Allylboration of Iminoisatins

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0635
Stereospecific Rhodium-Catalyzed Allylic Alkylation

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0636
Transition-Metal-Free Direct C–H Arylation of Quinoxalin-2(1H)-ones

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0637
Diastereoselective Synthesis of anti- and syn-β-Aminonitriles

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0638
Rearrangements of Cyclopropanols

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0639
Iron-Catalyzed Borylation

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0640
Iron-Promoted Hydroalkynylation

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0641
Synthesis of 3-Aryl or Alkyl 1,2-Benzisoxazoles

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0642
Iron-Catalyzed C–C Bond-Forming Spirocyclizations

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0643
Synthesis of Functionalized β-Keto Aryl Thioethers

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0644
Transition-Metal-Free Diboration

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Organo- and Biocatalysis
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Silylium Ion Catalyzed C–H Arylation of Hydrocarbons FREE ACCESS

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0646
Brønsted Acid Catalyzed Hydro-functionalization of Unactivated Alkynes

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0647
Brønsted Acid Catalyzed [2+2] Photocycloaddition Reactions

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0648
Regioselective Organocatalytic Olefin Hydroamination with 1,2,3-Triazoles

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0649
Catalytic Enantioselective N-Alkylation of Indoles by Aza-para-quinone Methides

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0650
Asymmetric Catalysis via Cyclic Aliphatic Oxocarbenium Ions

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0651
N-Heterocyclic Carbene Catalyzed Truce–Smiles Rearrangement

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0652
C–H Pyridination with Organoselenium Catalysts

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0653
A Systematic Investigation of Intramolecular Sulfenofunctionalizations of Alkenes

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0654
Visible-Light-Promoted [2+2+2] Cyclization of Alkynes with Nitriles

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0655
Organocatalytic Redox Deracemization of Cyclic Benzylic Ethers

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Polymer-Supported Synthesis
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0657
One-Pot Cascade Reaction Using Crosslinked Lipase-Supported Palladium Nanoparticles

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0658
Synthesis of Pyranodipyrazolones on Graphite Oxide Supported Silver Nanoparticles

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0659
Heck and Sonogashira Reactions on Magnetic Cobalt Nanoparticles FREE ACCESS

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0660
Alkyne Activation by a Porous Polymeric Silver Catalyst

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0661
Aerobic Oxidation of Benzylic Alcohols on Cu–Pd Nanoparticles

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Flow Dehydration and Hydrogenation of Allylic Alcohols

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Rapid Cyanosilylation of Ketones on Montmorillonite K10

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Heck Reaction on Palladium Nanoparticles Supported on Polymer-Modified Silica

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Semihydrogenation of Alkynes on Silica-Supported Cobalt Nanoparticles

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Hydrogenation of Nitroarenes on Platinum–Tin Oxide Core–Shell Nanoparticles

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Microporous Polymer Supported Palladium Catalyst for Oxidative Heck Reactions

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0668
An Immobilized Bisphosphine as Efficient Ligand in Co, Ni, and Cu Catalysis

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0669
Heterogeneous Copper Catalysts for the Synthesis of Indole-2-Carboxylic Esters

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0670
Hydrogenation of N-Heterocycles on ‘Naked’ Iridium(IV) Oxide Nanoparticles

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0671
Hydrogenation of Nitrobenzenes over γ-Fe₂O₃/Mesoporous Carbon

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Erratum
672
Total Synthesis of (±)-Andirolide N

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