Synfacts

Issue 06 · June 2018

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SYNFORM ISSUE 2018/06 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
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0553
Syntheses of Daphniphyllum Alkaloids FREE ACCESS

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0554
Synthesis of Verubecestat

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0555
Synthesis of Verubecestat FREE ACCESS

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0556
Total Synthesis of (–)-Lagunamide A

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0557
Total Synthesis of (+)-Arenolide

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0558
Synthesis of (±)-Sinensilactam A

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0559
Synthesis of α-Amanitin

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0560
Synthesis of (S)-Omeprazole

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0561
Synthesis of GDC-0575

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0562
Synthesis of PF-06424439

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0563
Synthesis of Entecavir

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0564
Synthesis of (+)-Siladenoserinol A

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0565
Synthesis of LY426965

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Synthesis of Heterocycles
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0567
Heterocycles by NHC-Catalyzed Aerobic Oxidative Annulation

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0568
Ligand-Free Catalytic Synthesis of Heterocyclic Sulfones

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0569
Vanadium-Promoted Stereoselective Radical Cyclizations to Tetrahydrofurans

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0570
Photocatalyzed Synthesis of Sulfonated Isoindolinones

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0571
Enantioselective [5+2] Annulations with a Cooperative Catalytic System FREE ACCESS

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0572
Transition-Metal-Free Synthesis of 1,3,5-Triazines

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0573
Enantioselective Friedel–Crafts Alkylation of Indoles

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0574
Cobalt–Carbene-Catalyzed Synthesis of Indolines

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0575
Ruthenium-Catalyzed Remote C–H Activation of Purines

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0576
N2-Selective CuO-Catalyzed Coupling of 1H-Indazoles with Diaryliodonium Salts

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0577
One-Step Syntheses of 1,4-Diazo Hetero-cycles by Formal [n+2] Cyclizations (n = 4–6)

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0578
Dibenzo[f,h]quinolines by Palladium-Catalyzed Decarboxylative Annulation

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0579
Michael Addition/[1,2]-Stevens Rearrangement Approach to Piperidines

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0580
Synthesis of Oxindolylidene Acetates and Spirooxindolopyrrolidones

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Synthesis of Materials and Unnatural Products
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0581
Metal-Free Routes for Biaryls

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0582
Aromatic Diels–Alder Annulations Achieved with the Help of the Sun

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0583
A Nanographene Propeller with [7]Helicene Blades

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0584
Golden Key Unlocks Internal Alkyne Reactivity in Push-Pull Systems

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0585
Fluorophore with Two-Photon-Excited and Emissive Behaviors in the NIR Region

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0586
Ambiphilicity of Dibromodihydropentacene

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0587
Two-Fold Hydroarylation Makes Indolizine

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0588
A Super Method to Utilize Ethylene as a C₂ Building Block

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0589
π-Extended Helicene with Quantum Yield >80%

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0590
Controlled Polymerization with the MIDA’s Touch

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0591
Red-Emissive Carbon-Bridged Triangulenium Dyes with Long Lifetime

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0592
Trichlorosilane Paves the Way from Phosphoric Acid to Phosphorous Molecules

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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0593
Iridium-Catalyzed Alkylation of Allenylic Electrophiles FREE ACCESS

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0594
Synthesis of Enantioenriched 2,3-Disubstituted Indolines

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0595
Nickel-Catalyzed Asymmetric C–H Functionalization of Pyridones FREE ACCESS

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0596
Rhodium-Catalyzed Enantioselective Alkenylation of Cyclic Ketimines

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0597
Rh-Catalyzed Asymmetric Addition of Aryl-boronic Acids to α,β-Unsaturated Ketimines

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0598
Palladium-Catalyzed Diastereoselective Synthesis of Imidazolidines

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0599
Enantioselective Cyclopropanation of α-Azo Rhodium Carbenoids and Styrenes

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0600
Palladium–Catalyzed Unsymmetrical Bis-Silylation of Alkynes

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0601
Ru-Catalyzed Dynamic Kinetic Resolution of α-Substituted β-Keto Sulfonamides

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0602
Hybrid Phosphorus Ligands for Anti-Markovnikov Hydroformylation

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0603
Design of a Bifunctional Chiral Phenanthroline Ligand

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0604
Copper-Catalyzed Decarboxylative β-Amino Alcohol Synthesis

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0605
Aza-Friedel–Crafts Addition of Phenols to N‑Sulfonyl Aldimines

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0606
Rhodium-Catalyzed Desymmetrization of Oxa- and Azabenzonorbornadienes

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0607
Copper-Catalyzed Enantioselective Friedel–Crafts Alkylation

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0608
Enantio- and Diastereoselective Hydrogenation of α‑Substituted β‑Keto Esters

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0609
Enantioselective Allylic Alkylation of 4-Substituted Isoxazolidin-5-ones

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0610
Copper-Catalyzed Regio- and Enantio-selective Aminoboration of Alkenes

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0611
Iron-Catalyzed Hydrosilylation of Unactivated Terminal Alkenes

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0612
Palladium-Catalyzed Synthesis of Chiral-at-Cage Carboranes

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0613
Platinum-Catalyzed Asymmetric Hydrosilylation of Alkenylboronates

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0614
Asymmetric Catalytic Hydrocarbo-functionalization of Nonactivated Alkenes

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0615
Palladium-Catalyzed Trifluoromethyl Indoline Synthesis with Sulfur Ylides

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0616
Asymmetric Desymmetrization of Cyclopentenediones

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0617
Enantioselective Rhodium–Catalyzed [2+2] Cycloaddition of Allenamides

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0618
Rh(II)/Sc(III) Co-catalyzed Multi-component Synthesis of γ-Sulfur-Substituted Ketones

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0619
Chiral Pyridoferrocenes by Imidoylative C–H Bond Activation Reaction

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0620
Asymmetric Synthesis of Alkyl Aryl(cyano)-[hydroxy(pyridin-2-yl)amino]acetates

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0621
Palladium-Catalyzed Asymmetric 1,6-Conjugate Addition of Arylboronic Acids

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0622
Stereoselective Friedel–Crafts/Michael Cascade Reaction by Gold Catalysis

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Metal-Mediated Synthesis
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0623
Trifluoromethylation of Sulfinamides with Fluoroform

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0624
Palladium-Catalyzed Cross-Coupling of Alkylindium Reagents

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0625
Synthesis of [¹¹C]Nitriles from Arylboronic Acids and Arylstannanes

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0626
Nickel-Catalyzed Cross-Coupling for the Difluoromethylation of Aromatics

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0627
Transition-Metal-Free Cross-Coupling of Bis(Sulfones) and Organolithium Reagents

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0628
Cyanotrifluoromethylthiolation of Alkynes via Cyano Migration

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0629
Synthesis of N-Heterocycles with Continuous Flow Photochemistry

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0630
Directed ortho-Metalation and ortho-Fries Rearrangement of Chrysenes

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0631
Cyclopropylation of Phenols and Azaheterocycles

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0632
Halogen Dance of Bromothiophenes

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0633
Nickel-Catalyzed Dearomative Carboamination

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0634
Asymmetric Cascade Reaction for the Synthesis of Tetrahydropyrans

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0635
Nickel-Catalyzed Cross-Coupling of Enol Ethers

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0636
Synthesis of Nitrosobenzene Derivatives from TMS-Substituted Benzenes

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0637
Formation of α-Quaternary Aldehydes by Formylation of Allylzinc Reagents

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Organo- and Biocatalysis
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0639
Cation Radical Diels–Alder Reactions via Asymmetric Counteranion-Directed Catalysis FREE ACCESS

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0640
Access to Enantioenriched Organosilanes from Enals and β-Silyl Enones

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0641
Acridinium-Mediated Photocatalytic Aliphatic C–H Functionalization

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0642
Mild Friedel–Crafts Alkylation Inside a Hexameric Resorcinarene Capsule

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0643
Hypervalent Iodine Derivatives as Halogen Bonding Based Organocatalysts

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0644
Ammonia Lyase Catalyzed Synthesis of Electron-Rich l-Phenylalanines

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0645
Chiral Aryl Iodide Catalyzed Fluoroamination of Cinnamyl Derivatives

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0646
Selenide-Catalyzed Asymmetric Construction of C–SCF₃ Bonds

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0647
Superbase-Catalyzed Anti-Markovnikov Addition Reactions

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Polymer-Supported Synthesis
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0649
Pt-Catalyzed Chemoselective Hydrogenation of Dienes and Nitroarenes FREE ACCESS

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0650
Photocatalytic C–N Bond Activation and Cross-Coupling of Anilines

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0651
Graphitic Carbon Nitride–Magnetite Nanocatalyst for the Synthesis of 4H-Pyrans

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0652
Ag–Cu/Metal Oxide Framework for Carboxy-lative Cyclization of Propargylic Compounds

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0653
Mukaiyama Aldol Reaction with Iron-Modified Mesoporous Silica

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0654
Cobalt-Catalyzed Aerobic Oxidation of Benzylic Alcohols

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0655
Dehydrative Cross-Etherification of Alcohols on a Tungsten–Titanium Mixed Oxide

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0656
Photocatalytic Aerobic Oxidative Coupling of Amines on a Metal–Organic Framework

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0657
Palladium-Catalyzed Formal Cross-Coupling of Diaryl Ethers and Amines

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0658
Microwave-Assisted Continuous-Flow Mizoroki–Heck Reaction

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0659
Benzylic Homocoupling of Alkylbenzenes on a Pt–Pd Bimetal Catalyst

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0660
Synthesis of Benzimidazoles by a Palladium-Catalyzed Hydrogen Transfer

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0661
Chemoselective Hydrogenation of Nitroarenes on Cobalt Phosphide/Carbon Nanocubes

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0662
Chemoselective Hydrogenation of Nitro-arenes on Supported Nickel Nanoparticles

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