DOI:
10.1055/s-00000084
Synthesis
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Interestingly, bromo-, chloro- and iodobenzene all show some activity in iron-catalysed borylation with B2pin2, activated with t-BuLi, generating PhBpin, albeit in low yields, showing that simple aryl halides are not entirely immune to cross-coupling processes. See: Bedford RB, Brenner PB, Carter E, Gallagher T, Murphy DM, Pye DM.
Organometallics 2014;
33: 5940
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