DOI:
10.1055/s-00000084
Synthesis
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For monosubstituted cyclopropenes possessing a substituent able to stabilize an adjacent positive charge, theoretical studies show that binding of a cationic gold–phosphine complex occurs in an unsymmetrical fashion through the unsubstituted carbon and subsequent kinetically controlled ring opening leads to the less substituted gold carbenoid, see: Hadfield MS, Häller LJ. L, Lee A.-L, Macgregor SA, O’Neill JA. T, Watson AM.
Org. Biomol. Chem. 2012;
10: 4433
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