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Synfacts 2011(9): 1000-1000
DOI: 10.1055/s-0030-1260887
DOI: 10.1055/s-0030-1260887
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New YorkAccess to Benzyl Boronates via Suzuki Coupling of Diborylmethane
K. Endo*, T. Ohkubo, T. Shibata*
Waseda Institute for Advanced Study, Tokyo, PRESTO, Japan Science and Technology Agency, Saitama and Waseda University, Tokyo, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
19. August 2011 (online)
Significance
The authors report a chemoselective Pd-catalyzed Suzuki-Miyaura coupling of a range of substituted aryl bromides with methylene-bis(pinacolato)boron. Various benzyl boronate derivatives are accessible by this method. Notably, also highly bulky substituents on the aryl bromide can be present.