Transition-Metal-Catalyzed Stereo- and Regioselective Hydrosilylation of Unsymmetrical Alkynes

Peng He; Meng-Yang Hu; Xin-Yu Zhang; Shou-Fei Zhu

doi:10.1055/a-1605-9572

Synthesis, Table of Contents

Synthesis 2022; 54(01): 49-66
DOI: 10.1055/a-1605-9572

short review

Transition-Metal-Catalyzed Stereo- and Regioselective Hydrosilylation of Unsymmetrical Alkynes

Authors

Peng He
Meng-Yang Hu
Xin-Yu Zhang
Shou-Fei Zhu ∗

Abstract

All articles of this category

Dedicated to the 100^th Anniversary of Chemistry at Nankai University.

Abstract

Alkyne hydrosilylation is one of the most efficient methods for the synthesis of alkenyl silicon derivatives and has been a hot topic of research for decades. This short review summarizes the progress in transition-metal-catalyzed stereo- and regioselective hydrosilylation of unsymmetrical alkynes. Topics are discussed based on different types of alkynes and the selectivities.

1 Introduction

2 Terminal Alkyne Hydrosilylation

2.1 β-E Selectivity

2.2 β-Z Selectivity

2.3 α-selectivity

3 Internal Alkyne Hydrosilylation

3.1 Aryl–Alkyl Acetylenes

3.2 Alkyl–Alkyl Acetylenes

3.3 Internal Alkynes with Polarized Substituents

4 Summary and Outlook

Key words

hydrosilylation - transition-metal catalysts - alkynes - alkenyl silicons - selectivity

Full Text

References

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