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Synthesis 2017; 49(07): 1419-1443
DOI: 10.1055/s-0036-1589478
DOI: 10.1055/s-0036-1589478
review
Recent Developments in Cobalt Catalyzed Carbon–Carbon and Carbon–Heteroatom Bond Formation via C–H Bond Functionalization
Authors
Further Information
Publication History
Received: 19 September 2016
Accepted after revision: 19 October 2016
Publication Date:
06 February 2017 (online)
Abstract
Cobalt catalysts have evolved to be seen as versatile eco-compatible and economical
catalysts in organic synthesis in recent years. Cobalt-catalyzed reactions are undoubtedly
a classic in synthetic chemistry for the formation of carbon–carbon and carbon–heteroatom
bonds. Another important aspect in this field is catalyst variants, such as low-valent
and high-valent cobalt catalysts. This review summarizes the recent progress and synthetic
utility of low-valent and high-valent cobalt catalysts towards C–H functionalization
processes achieving C–C, C–O, C–N and C–B bond formation. Mechanistic insight is also
discussed, with the goal of serving as a stepping stone for further development in
this field. In addition, Csp3–H bond functionalization reactions provide many opportunities for novel synthesis
approaches.
1 Introduction
2 Carbon–Carbon Bond Formation
2.1 Csp2–Csp3 Bond Formation
2.2 Csp2–Csp2 Bond Formation
3 Carbon–Nitrogen Bond Formation
4 Csp3–H Bond Functionalization
5 Carbon–Oxygen Bond Formation
6 Carbon–Boron Bond Formation
7 Conclusion
-
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For references on Co(I)-catalysis, see:
For cobalt-catalyzed hydrosilylation, see: