Synthesis 2022; 54(12): 2799-2815
DOI: 10.1055/a-1767-3026
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Ferrocenephosphonates: Copper-Promoted Synthesis and Further Functionalization

Kmar Abaid
a   Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France
b   University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Hetero-Organic Compounds and Nanostructured Materials (LR18ES11), 7021, Jarzouna, Tunisia
,
William Erb
a   Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France
,
Marielle Blot
a   Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France
,
Thierry Roisnel
a   Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France
,
a   Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, F-35000 Rennes, France
,
Soufiane Touil
b   University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Hetero-Organic Compounds and Nanostructured Materials (LR18ES11), 7021, Jarzouna, Tunisia
› Author Affiliations
This work was supported by the Université de Rennes 1, Centre National de la Recherche Scientifique (CNRS), the University of Carthage, the Ministère de l’Enseignement Supérieur et de la Recherche Scientifique (Tunisian Ministry of Higher Education and Scientific Research; grant for K. A.), and the Fonds Européen de Développement Régional (FEDER; European Regional Development Fund; D8 VENTURE Bruker AXS diffractometer).


Abstract

Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferrocenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki–Miyaura cross-coupling reactions are also described to reach original derivatives.

Supporting Information



Publication History

Received: 19 January 2022

Accepted after revision: 09 February 2022

Accepted Manuscript online:
09 February 2022

Article published online:
05 April 2022

© 2022. Thieme. All rights reserved

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