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CC BY 4.0 · Synthesis 2023; 55(09): 1375-1384
DOI: 10.1055/a-1997-0939
DOI: 10.1055/a-1997-0939
special topic
Bürgenstock Special Section 2022 – Future Stars in Organic Chemistry
Samarium and Ytterbium in Organic Electrosynthesis
Financial support from Vetenskapsrådet (Swedish Research Council) (Grant no. 2021-05551), Svenska Forskningsrådet Formas (Grant no. 2021-00678), Stiftelsen för Strategisk Forskning (Swedish Foundation for Strategic Research) (Grant no. FFL21-0005), Stiftelsen Olle Engkvist Byggmästare, Magnus Bergvalls Stiftelse, Stiftelsen Lars Hiertas Minne, and Kungliga Tekniska Högskolan (KTH Royal Institute of Technology) is gratefully acknowledged.
Abstract
Low-valent lanthanide catalysts and reagents are well-established as versatile and tunable mediators for a variety of synthetic transformations. Despite the contemporary interest in electricity as a sustainable alternative to stoichiometric redox reagents, electrochemical (re)generation of such low-valent metal complexes in a synthetic setting is surprisingly limited. With focus on samarium and ytterbium, this review presents a comprehensive overview of electroreductive-mediated transformations with the hope of inspiring further work in this very useful field of research.
1 Introduction
2 Compounds Containing Carbon–Oxygen Bonds
2.1 Ethers
2.2 Aldehydes and Ketones
2.3 Esters and Phthalimides
3 Compounds Containing Nitrogen–Oxygen Bonds
4 Compounds Containing Carbon–Halide Bonds
5 Conclusions
Publication History
Received: 30 November 2022
Accepted after revision: 13 December 2022
Accepted Manuscript online:
13 December 2022
Article published online:
27 March 2023
© 2022. This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by/4.0/)
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