Efficient Palladium-Catalyzed
Coupling of Baylis-Hillman Acetates with an Allylstannane

Jinhyung Park; Young Bum Kwon; Kyungmo Yang; Hakjune Rhee; Cheol Min Yoon

doi:10.1055/s-0029-1218612

PAPER

Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane

Jinhyung Park^a, Young Bum Kwon^a, Kyungmo Yang^a, Hakjune Rhee^b, Cheol Min Yoon*^a
^a Department of Advanced Material Chemistry, Korea University, Jochiwon, Choongnam 339-700, South Korea
Fax: +81(41)8675396; e-Mail: cmyoon@korea.ac.kr;
^b Department of Chemistry & Applied Chemistry, Hanyang University, Sangrok-Gu, Ansan, Kyunggi-Do 426-791, South Korea

Abstract

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Abstract

Acetates of Baylis-Hillman adducts derived from ethyl acrylate, methyl vinyl ketone, and acrylonitrile were coupled with allyltributylstannane using Pd(PPh₃)₄ or Pd(dba)₂ as the catalyst at room temperature to afford the corresponding trisubstituted alka-1,5-dienes in good to high yields.

Key words

Baylis-Hillman acetates - allyltributylstannane - bis-π-allylpalladium - 1,5-diene - allylation

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References

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