Advances in the Direct Amination
of Azole C-H Bonds

Ming Zhang

doi:10.1055/s-0030-1260231

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Synthesis 2011(21): 3408-3417
DOI: 10.1055/s-0030-1260231

REVIEW

Advances in the Direct Amination of Azole C-H Bonds

Ming Zhang*
College of Chemistry, Jiangxi Normal University , (Yaohu Campus), 99 Ziyangdadao, Nanchang, Jiangxi 330022, P. R. of China
Fax: +86(189)79135351; e-Mail: zmchem@163.com;

Further Information

Publication History

Received 17 July 2011
Publication Date:
20 September 2011 (online)

Abstract
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Abstract

The direct amination of azole C-H bonds provides a straightforward, effective access to nitrogen group containing azoles without the prefunctionalization of azoles. This review discussed the rapid advances in the direct amination of azoles; copper-catalyzed/mediated amination, acid-promoted amination, and metal-free amination are discussed.

1 Introduction

2 Copper-Catalyzed/Mediated Amination

3 Acid-Promoted Amination

4 Metal-Free Amination

5 Conclusions

Key words

amides - amines - amination - coupling - heterocycles

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