Synlett 2014; 25(12): 1731-1734
DOI: 10.1055/s-0033-1341272
letter
© Georg Thieme Verlag Stuttgart · New York

Silver-Mediated Radical Trifluoromethylarylation of Activated Alkenes for the Synthesis of Oxindoles Bearing a CF3 Group

Yao-Feng Wang
Department of Applied Chemistry, School of Chemical Engineering & the Environment, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing 100081, P. R. of China   Fax: +86(10)68918296   eMail: fuxue.chen@bit.edu.cn
,
Jiashen Qiu
Department of Applied Chemistry, School of Chemical Engineering & the Environment, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing 100081, P. R. of China   Fax: +86(10)68918296   eMail: fuxue.chen@bit.edu.cn
,
Dejie Kong
Department of Applied Chemistry, School of Chemical Engineering & the Environment, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing 100081, P. R. of China   Fax: +86(10)68918296   eMail: fuxue.chen@bit.edu.cn
,
Fu-Xue Chen*
Department of Applied Chemistry, School of Chemical Engineering & the Environment, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing 100081, P. R. of China   Fax: +86(10)68918296   eMail: fuxue.chen@bit.edu.cn
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Publikationsverlauf

Received: 21. März 2014

Accepted after revision: 28. März 2014

Publikationsdatum:
12. Mai 2014 (online)


Abstract

A radical trifluoromethylarylation of N-arylacrylamides with in situ generated [AgCF3] species from Me3SiCF3 and AgF in DMF is established through a tandem radical addition and C–H activation pathway. It provided a concise method to prepare 21 examples of CF3-containing oxindoles within four hours.

Supporting Information

 
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