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Synthesis 2015; 47(19): 2945-2956
DOI: 10.1055/s-0034-1378862
DOI: 10.1055/s-0034-1378862
special topic
Simple Method for sp2–sp3 and sp3–sp3 Carbon–Carbon Bond Activation in 2-Substituted 1,3-Diketones
Further Information
Publication History
Received: 30 April 2015
Accepted after revision: 05 June 2015
Publication Date:
29 July 2015 (online)
Abstract
Simple and efficient methods were developed for sp2–sp3 and sp3–sp3 C–C bond-activation reactions of 2-substituted 1,3-diketones. 3-Substituted 3-bromopentane-2,4-diones were deacylated in the presence of an aromatic compound and a silica gel supported Brønsted acid containing sulfonic groups. The carbocation formed by cleavage of the sp3–sp3 C–C bond of the dione alkylated the aromatic compound.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1378862.
- Supporting Information
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