Synlett 2015; 26(08): 997-1002
DOI: 10.1055/s-0034-1380167
synpacts
© Georg Thieme Verlag Stuttgart · New York

Recent Development in N-Auxilixary-Assisted Intramolecular Amination for Amine Substrates

Chao Wang
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China   eMail: yszhao@suda.edu.cn
,
Jian Han
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China   eMail: yszhao@suda.edu.cn
,
Yingsheng Zhao*
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China   eMail: yszhao@suda.edu.cn
› Institutsangaben
Weitere Informationen

Publikationsverlauf

Received: 25. November 2014

Accepted after revision: 07. Januar 2015

Publikationsdatum:
09. Februar 2015 (online)


Abstract

Direct coupling of N–H with C–H has aroused great attention in the last decades; during which the directing-group-assisted intramolecular C–N bond formation via transition metal has been achieved significant progress. Herein, we highlight the recent development in the directing-group-assisted intramolecular amination for amine substrates to build the important N-containing heterocyclic compounds.

1 Introduction

2 Triflamide-Promoted Intramolecular Amination

3 Picolinamide-Assisted Intramolecular Amination

4 Palladium-Catalyzed Intramolecular Amination under Assistance of Oxalyl Amide

5 Conclusion

 
  • References

    • 1a Jensen T, Fristrup P. Chem. Eur. J. 2009; 15: 9632
    • 1b Lyons TW, Sanford MS. Chem. Rev. 2010; 110: 1147
    • 1c Bras JL, Muzart J. Chem. Rev. 2011; 111: 1170
    • 1d Wendlandt AE, Suess AM, Stahl SS. Angew. Chem. Int. Ed. 2011; 50: 11062
    • 1e Broggini G, Beccalli EM, Fasana A, Gazzola S. Beilstein J. Org. Chem. 2012; 8: 1730
    • 1f Yuan J, Liu C, Lei A. Chem. Commun. 2015; 51: 1394
    • 2a Dick AR, Hull KL, Sanford MS. J. Am. Chem. Soc. 2004; 126: 2300
    • 2b Hull KL, Lanni EL, Sanford MS. J. Am. Chem. Soc. 2006; 128: 14047
    • 2c Chen X, Goodhue CE, Yu J.-Q. J. Am. Chem. Soc. 2006; 128: 12634
    • 3a Desai LV, Hull KL, Sanford MS. J. Am. Chem. Soc. 2004; 126: 9542
    • 3b Thu H.-Y, Yu W.-Y, Che C.-M. J. Am. Chem. Soc. 2006; 128: 9048
    • 3c Kang T, Kim Y, Lee D, Wang Z, Chang S. J. Am. Chem. Soc. 2014; 136: 4141
    • 3d Ren Z, Mo F, Dong G. J. Am. Chem. Soc. 2012; 134: 16991
    • 4a Daugulis O, Zaitsev VG. Angew. Chem. Int. Ed. 2005; 44: 4046
    • 4b Wan X, Ma Z, Li B, Zhang K, Cao S, Zhang S, Shi Z. J. Am. Chem. Soc. 2006; 128: 7416
    • 4c Wasa M, Engle KM, Yu J.-Q. J. Am. Chem. Soc. 2009; 131: 9886
    • 4d Wang D.-H, Hao X.-S, Wu D.-F, Yu J.-Q. Org. Lett. 2006; 8: 3387
    • 5a Giri R, Yu J.-Q. J. Am. Chem. Soc. 2008; 130: 14082
    • 5b Wang D.-H, Engle KM, Shi B.-F, Yu J.-Q. Science 2010; 327: 315
    • 6a Lu Y, Wang D.-H, Engle KM, Yu J.-Q. J. Am. Chem. Soc. 2010; 132: 5916
    • 6b Wang X, Lu Y, Dai H.-X, Yu J.-Q. J. Am. Chem. Soc. 2010; 132: 12203
    • 6c Xiao B, Gong T.-J, Liu Z.-J, Liu J.-H, Luo D.-F, Xu J, Liu L. J. Am. Chem. Soc. 2011; 133: 9250
    • 7a Giri R, Liang J, Lei J.-G, Li J.-J, Wang D.-H, Chen X, Naggar IC, Guo C, Foxman BM, Yu J.-Q. Angew. Chem. Int. Ed. 2005; 44: 7420
    • 7b Li G, Leow D, Wan L, Yu J.-Q. Angew. Chem. Int. Ed. 2013; 52: 1245
    • 7c Murai S, Kakiuchi F, Sekine S, Tanaka Y, Kamatani A, Sonoda M, Chatani N. Nature (London, U.K.) 1993; 366: 529
    • 7d Kakiuchi F, Murai S. Acc. Chem. Res. 2002; 35: 826

      For recent reviews, see:
    • 8a Kakiuchi F, Murai S. Acc. Chem. Res. 2002; 35: 826
    • 8b Godula K, Sames D. Science 2006; 312: 67
    • 8c Lyons TW, Sanford MS. Chem. Rev. 2010; 110: 1147
    • 8d MaNally A, Prier CK, MacMillan DW. C. Science 2011; 334: 1114
    • 8e McMurray L, O’Hara F, Gaunt MJ. Chem. Soc. Rev. 2011; 40: 1885
    • 8f Engle KM, Mei T.-S, Wasa M, Yu J.-Q. Acc. Chem. Res. 2011; 45: 788
    • 8g Li B.-J, Shi Z.-J. Chem. Soc. Rev. 2012; 41: 5588
    • 8h Mousseau JJ, Charette AB. Acc. Chem. Res. 2012; 46: 412
    • 8i Yamaguchi J, Yamaguchi AD, Itami K. Angew. Chem. Int. Ed. 2012; 51: 8960
    • 8j Rouquet G, Chatani N. Angew. Chem. Int. Ed. 2013; 52: 11726
    • 8k Louillat M.-L, Patureau FW. Chem. Soc. Rev. 2014; 43: 901
  • 9 Mei T.-S, Wang X, Yu J.-Q. J. Am. Chem. Soc. 2009; 131: 10806
  • 10 He G, Zhao Y, Zhang S, Lu C, Chen G. J. Am. Chem. Soc. 2012; 134: 3
  • 11 Nadres ET, Daugulis O. J. Am. Chem. Soc. 2012; 134: 7
  • 12 Ye X, He Z, Ahmed T, Weise K, Akhmedov NG, Petersen JL, Shi X. Chem. Sci. 2013; 4: 3712
  • 13 Li J.-J, Mei T.-S, Yu J.-Q. Angew. Chem. Int. Ed. 2008; 47: 6452
  • 14 Mei T.-S, Leow D, Xiao H, Laforteza BN, Yu J.-Q. Org. Lett. 2013; 15: 3058
  • 15 Yang M, Su B, Wang Y, Chen K, Jiang X, Zhang Y.-F, Zhang X.-S, Chen G, Cheng Y, Cao Z, Guo Q.-Y, Wang L, Shi Z.-J. Nat. Commun. 2014; 5: 4707
  • 16 He G, Lu C, Zhao Y, Nack WA, Chen G. Org. Lett. 2012; 14: 2944
  • 17 Wang C, Chen CP, Zhang JY, Han J, Wang Q, Guo K, Liu P, Guan MY, Yao YM, Zhao YS. Angew. Chem. Int. Ed. 2014; 53: 9884
    • 18a Wang Q, Han J, Wang C, Zhang JY, Huang ZB, Shi DQ, Zhao YS. Chem. Sci. 2014; 5: 4962
    • 18b Han J, Liu P, Wang C, Wang Q, Zhang JY, Zhao YW, Shi DQ, Huang ZB, Zhao YS. Org. Lett. 2014; 16: 5682