Synthesis
DOI: 10.1055/s-0036-1588580
psp
© Georg Thieme Verlag Stuttgart · New York

Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane

Joseph A. Buonomo, Carter G. Eiden, Courtney C. Aldrich*
  • University of Minnesota, Department of Medicinal Chemistry, Weaver-Densford Hall, 308 Harvard St. SE Minneapolis, MN 55455, USA   Email: aldri015@umn.edu
Further Information

Publication History

Received: 02 September 2017

Accepted after revision: 06 September 2017

Publication Date:
26 September 2017 (eFirst)

Abstract

A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to hydrido-disiloxanes from widely accessible commercially available silanes.

Supporting Information

 
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