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Synthesis 2018; 50(16): 3197-3204
DOI: 10.1055/s-0036-1591596
DOI: 10.1055/s-0036-1591596
special topic
Palladium-Catalyzed Decarboxylative Coupling Reactions of Propiolic Acid Derivatives and Arylsulfonyl Hydrazide
This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (NRF-2015R1A4A1041036, NRF-2017R1A2B2002929).
Weitere Informationen
Publikationsverlauf
Received: 07. Mai 2018
Accepted after revision: 29. Mai 2018
Publikationsdatum:
16. Juli 2018 (online)
Published as part of the Special Topic Modern Coupling Approaches and their Strategic Applications in Synthesis
Abstract
Arylsulfonyl hydrazides were employed as coupling partners for the decarboxylative coupling reaction of propiolic acid derivatives. When the reaction was conducted using Pd(TFA)2 (1.0 mol%), dppp (1.0 mol%), and Cu(OAc)2 (2.4 equiv) in DMF at 100 °C for 0.5 hour, the desired coupled products were formed in moderate to good yields. The reaction showed good tolerance toward functional groups such as ester, ketone, cyano, nitro, chloro, and bromo groups.
Keywords
decarboxylative coupling - propiolic acid - arylsulfonyl hydrazide - palladium - arylalkyneSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1591596.
- Supporting Information
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