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Synthesis 2018; 50(19): 3809-3824
DOI: 10.1055/s-0037-1610107
DOI: 10.1055/s-0037-1610107
short review
Recent Advances in the Applications of Triethylsilane in Organic Synthesis
This work was supported by the National Program of Sustainability (project LO1304).Further Information
Publication History
Received: 06 April 2018
Accepted after revision: 11 May 2018
Publication Date:
02 July 2018 (online)
Abstract
The synthesis of pharmacologically relevant scaffolds is an important goal in modern organic chemistry. For this reason, the use of methodologies involving operationally simple procedures and easily handled reagents to chemoselectively and stereoselectively convert different functionalities has gained considerable attention. In this review, we summarize the latest trends in reductive reactions using triethylsilane as the key reagent that provide synthetically interesting intermediates, coupling products and structures with control of the 3D architecture.
1 Introduction
2 Scenario A: Reduction of C–C Multiple Bonds
3 Scenario B: Reduction of Functional Groups
4 Scenario C: Reductive Coupling
5 Scenario D: Reductive Cyclization
6 Conclusion
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