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CC BY-ND-NC 4.0 · Synlett 2019; 30(04): 370-377
DOI: 10.1055/s-0037-1610283
DOI: 10.1055/s-0037-1610283
account
Symmetric Multiple Carbohelicenes
This work was supported by the ERATO program from JST (JPMJER1302 to K.I.), the Funding Program for KAKENHI from MEXT (JP16K05771 to Y.S.), a grant-in-aid for Scientific Research on Innovative Areas ‘π-Figuration’ from JSPS (JP17H05149 to Y.S.), and the Noguchi Institute (to Y.S.). K.K. thanks IGER Program in Green Natural Sciences, Nagoya University and a JSPS fellowship for young scientists. Calculations were performed using the resources of the Research Center for Computational Science, Okazaki, Japan. ITbM is supported by the World Premier International Research Center Initiative (WPI), Japan.Further Information
Publication History
Received: 21 July 2018
Accepted after revision: 24 August 2018
Publication Date:
26 September 2018 (online)
Abstract
This account focuses on the synthesis and structures of symmetric multiple carbohelicenes; i.e., fully fused polycyclic aromatic hydrocarbons containing two or more symmetric helicene moieties. Synergies of the multiplexed helicene structures within a π-system generate a number of local minima and transition states between each state. Based on recent studies on multiple helicenes, a systematic molecular design for further multiplexed symmetric helicenes is proposed in the last section of this article.
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For reviews on helicenes, see:
For isomerization barriers of carbo[n]helicenes, see:
For long carbohelicenes, see:
For laterally extended helicenes, see:
For thiahelicenes, see:
For azahelicenes, see:
For other representative heterohelicenes, see:
For multiple helicenes that contain five-membered rings, see:
For multiple heterohelicenes, see:
For other polycyclic arenes that contain helicene moieties, see: