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Synthesis 2021; 53(15): 2602-2611
DOI: 10.1055/s-0040-1706743
DOI: 10.1055/s-0040-1706743
feature
Thia-Bridged Triarylamine[4]helicene-Functionalized Polynorbornenes as Redox-Active pH-Sensitive Polymers
Authors
The authors thank MIUR-Italy (‘Progetto Dipartimenti di Eccellenza 2018–2022’ allocated to Department of Chemistry ‘Ugo Schiff’, University of Florence, Italy) for financial support.
Abstract
A series of thia-bridged triarylamine[4]helicene-functionalized polynorbornenes P1, P2, and P3 were synthesized via ring-opening metathesis polymerization (ROMP). The polymers obtained undergo a reversible one-electron oxidation, in both solution and solid state, responding to the pH changes in the surrounding medium showing a clear reversible electrochromic behavior.
Key words
hetero[4]helicenes - radical cations - ROMP - pH-sensitive polymers - redox polymers - electrochromic polymersSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1706743.
- Supporting Information (PDF)
Publikationsverlauf
Eingereicht: 23. Dezember 2020
Angenommen nach Revision: 11. Februar 2021
Artikel online veröffentlicht:
11. März 2021
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