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Synlett 2020; 31(14): 1343-1348
DOI: 10.1055/s-0040-1707145
DOI: 10.1055/s-0040-1707145
synpacts
Force-Induced Cycloaddition of Aziridine: Can We Force a New Route?
This work was supported by the National Research Foundation of Korea (NRF-2019R1A6A1A11044070; NRF-2019R1A2C2011003).Further Information
Publication History
Received: 11 May 2020
Accepted after revision: 15 May 2020
Publication Date:
18 June 2020 (online)
Abstract
Cycloaddition reactions of aziridines with dipolarophiles under traditional thermal or photochemical conditions entail destructive routes to form reactive intermediates such as an azomethine ylide. This article highlights a recent study that demonstrates a cycloaddition reaction of aziridine induced by mechanical force. Experimental results suggest that the force-induced cycloaddition of aziridine with dimethyl acetylenedicarboxylate as a dipolarophile does not seem to involve an ylide, with implications for a possible new reaction route.
1 Rivalry between Aziridine and Epoxide
2 Mechanochemically Responsive Polymers
3 Aziridine Mechanophore
4 Concluding Remarks and Outlook
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