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CC BY-NC-ND 4.0 · Synthesis 2022; 54(07): 1817-1822
DOI: 10.1055/s-0040-1720891
DOI: 10.1055/s-0040-1720891
psp
[1,3]-Dithiolo-[4,5-d][1,3-dithiole]-2,5-dione
Financial support of this project by the ESRF is gratefully acknowledged.
Abstract
A safe, three-step reaction sequence to [1,3]-dithiolo-[4,5-d][1,3-dithiole]-2,5-dione starting from carbon disulfide is presented. Optimized reaction conditions, rigorous purification, and full characterization of all intermediates provide reproducibly a final product of superior quality with a melting point of 181 °C (dec.).
Key words
1,3,4,6-tetrathiapentalene-2,5-dione - thiapendione - 1,1,2,2-tetrathioethene - thermoelectricity - 2-oxo-1,3-dithiole-4,5-dithiolate - dmidSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1720891.
- Supporting Information
Publication History
Received: 28 July 2021
Accepted after revision: 31 August 2021
Article published online:
20 October 2021
© 2021. This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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