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Synthesis 1971; 1971(5): 229-235
DOI: 10.1055/s-1971-21706
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Diene Synthesis via Boronate Fragmentation

James A. MARSHALL*
  • *Department of Chemistry, Northwestern University, Evanston, Illinois 60201, U.S.A.
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Publikationsdatum:
12. September 2002 (online)

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The importance of 1,5-dienes as natural products and the available synthetic routes to such compounds are discussed. The development of a new route to 1,5- and 1,6-cyclodecadienes and acyclic 1,5-dienes through solvolytic fragmentation of boronic acid derivatives is described with particular emphasis on the factors which control the outcome of such reactions.