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Synthesis 1974; 1974(2): 90-113
DOI: 10.1055/s-1974-23249
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Syntheses via Oxyphosphoranes

Fausto RAMIREZ*
  • *Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11790, U.S.A.
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Publication History

Publication Date:
12 September 2002 (online)

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In this article structures, syntheses, and reactions of oxyphosphoranes are discussed. The reactions of phosphorus(III) derivatives with carbonyl compounds which result in isolable P(5) and P(4) products are described. Emphasis is placed on the chemical behaviour of 2,2,2-trialkoxy-2,2-dihydro-1,3,2-dioxaphospholenes and -phospholanes and other cyclic oxyphosphoranes. 1. Structure of Oxyphosphoranes 2. Nomenclature and Scope of the Review 3. Classification of Syntheses 4. Reactions of 3-coordinate Phosphorus, P(3), with Carbonyl compounds 5. Reactions of 2,2,2-Trialkoxy-2,2-dihydro-1,3,2-dioxaphospholenes 6. Reactions of 2,2,2-Trialkoxy-2,2-dihydro-1,3,2-dioxaphospholanes 7. Reactions of Other Oxyphosphoranes

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