Synthesis of Unsymmetrically Substituted Tetraphenylenes through Palladium-Catalyzed C(sp²)–H Activation

Abstract

An efficient protocol for the palladium-catalyzed cross-coupling reaction of 2-iodobiphenyls with biphenylene has been developed through C–H activation. The reaction provides a simple and efficient method for the synthesis of unsymmetrically substituted tetra­phenylenes.

Key words

palladium catalysis - C–H activation - tetraphenylenes - cross-coupling - unsymmetrical substitution

Publication History

Received: 14 January 2021

Accepted after revision: 08 March 2021

Accepted Manuscript online:
08 March 2021

Article published online:
01 April 2021

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