Synthesis 2022; 54(08): 1877-1907
DOI: 10.1055/a-1684-0031
review

Synthesis and Reactions of Borazines

Ishita Neogi
a   Photoscience and Photonics Section, Chemical Science and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (CSIR-NIIST), Thiruvananthapuram, 695019 India, India
b   Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002 India, India
,
c   Department of Chemical Sciences, Ariel University, 40700000 Ariel, Israel
› Author Affiliations
I.N. thanks DST, India (GAP 162039) for funding.


Abstract

Given the wide array of current applications of borazine-based materials, synthetic access to these compounds is of importance. This review summarizes the many ways of preparing borazines and its carbo-substituted analogues. In addition, the functionalization of borazines is covered. The synthesis of molecules incorporating more than one borazine units as well as aspects of unsymmetrically substituted borazines are not included. The literature has been covered comprehensively until the end of 2020.

1 Introduction: Structure and Properties of Borazine

2 Synthesis of Parent Borazine

3 Synthesis of N-Substituted Borazines

4 Synthesis of B-Halo/B-Halo-N-Substituted Borazines

5 Synthesis of B-Substituted Borazines

6 Synthesis of Polycyclic Borazines Containing One Borazine Ring

7 Modifications or Hydrolysis of the Borazine Ring

8 Borazine Metal Complexes

9 Outlook and Conclusion



Publication History

Received: 04 July 2021

Accepted after revision: 02 November 2021

Accepted Manuscript online:
02 November 2021

Article published online:
24 February 2022

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